株式会社 シン・コーポレーションIonotec社はイオン伝導性セラミックスとナトリウム電池技術の開発を専門とし、ベータアルミナセラミックスを製造し提供する企業です。ベータアルミナセラミックスは様々な形状とサイズで製造しています。また、規定の形状やサイズだけでなく、お客様のご要望に応じてカスタマイズも可能です。
また、英国に拠点を置く同社は、英国政府、または世界中の民間企業と数多くの研究開発プログラムを実施しています。
◎ お問合せの際には、ご希望の仕様（コード）、形状、サイズ、厚みなどをご連絡ください。形状・サイズによりますが、厚みは0.5mm～となります（μm単位の扱いはございません）。なお、メーカー最低発注金額があるため、複数での購入が必要な場合がございます。また、現在、Ionotec社では、二酸化ジルコニウムを含む強化組成の方をお勧めしております。
製品仕様
| 仕様コード | Stabiliser | Conductive Ion | Zirconia (Yes/No) | |||||
|---|---|---|---|---|---|---|---|---|
| LN | Lithium | Sodium | No | |||||
| LNZ | Lithium | Sodium | Yes | |||||
| LK | Lithium | Potassium | No | |||||
| LKZ | Lithium | Potassium | Yes | |||||
| LAg | Lithium | Silver | No | |||||
| LAgZ | Lithium | Silver | Yes | |||||
| LSr | Lithium | Strontium | No | |||||
| LSrZ | Lithium | Strontium | Yes | |||||
| MN | Magnesium | Sodium | No | |||||
| MNZ | Magnesium | Sodium | Yes | |||||
| MK | Magnesium | Potassium | No | |||||
| MKZ | Magnesium | Potassium | Yes | |||||
| MAg | Magnesium | Silver | No | |||||
| MAgZ | Magnesium | Silver | Yes | |||||
| MSr | Magnesium | Strontium | No | |||||
| MSrZ | Magnesium | Strontium | Yes | |||||
| ZrO2(二酸化ジルコニウム）の添加により微細構造における最大粒子径が小さく、強度が向上しています。 | ||||||||
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参考用仕様書
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形状
| ディスク | ||
|---|---|---|
| Shape | Maximum Diameter (mm) | Thickness* (mm) |
| Disc | 105 | 1.5-2.0 |
| Disc | 45 | 1.5-2.0 |
| Disc | 20 | 1.0-2.0 |
| Disc | 15 | 0.75-2.0 |
| Disc | 10 | 0.5-2.0 |
|
ディスクは大き目の材料からサイズに合わせて機械加工するため、10mm～105mmの範囲内のご希望の直径でご提供が可能です。直径により、可能な薄さは変わります。上記の通り、直径が大きくなるに従い、供給可能な最小の厚みは増加します。 |
||
| プレート（正方形・長方形） | ||
|---|---|---|
| Shape | Side length (mm) | Thickness (mm) |
| Plate | 70×70 | 1.5-2.0 |
| Plate | 40×40 | 1.5-2.0 |
| Plate | 20×20 | 1.0-2.0 |
| Plate | 15×15 | 0.75-2.0 |
| Plate | 12×12 | 0.5-2.0 |
| 正方形のプレートの品番は、下記例のように[P 一辺の長さ-厚み-仕様コード]で示されます。 例：P24-1-LN, P70-2-LK, P45-1.5-LNZ＊長方形のプレートは縦横の長さが表示されます。例：P20/50-1.5-LNZ |
||
| チューブ | ||||
|---|---|---|---|---|
| 形状コード | Maximum Length (mm) | Open end internal diameter (mm) | Closed end shape | Wall thickness (mm) |
| A1 | 70 | 6.5 | round | 0.5-1.5 |
| A2 | 100 | 13 | flat | 1.0-2.0 |
| A4 | 100 | 4 | round | 0.5-1.0 |
| H1 | 40 | 20 | flat | 1.0-2.0 |
| H3 | 80 | 20 | flat | 1.0-2.0 |
| H4 | 100 | 20 | flat | 1.0-2.0 |
| B1 | 100 | 28 | flat | 1.5-2.0 |
| B2 | 220 | 29 | flat | 1.5-2.0 |
| B8 | 220 | 31 | flat | 1.5-2.0 |
| B10 | 290 | 30 | flat | 1.5-2.0 |
| B11 | 260 | 35 | flat | 1.5-2.0 |
| C1 | 140 | 52 | round | 1.5-2.0 |
| C2 | 220 | 52 | round | 1.5-2.0 |
| C3 | 330 | 52 | round | 1.5-2.0 |
| C5 | 100 | 45.5 | round | 1.5-2.0 |
| C6 | 350 | 36.5 | round | 1.5-2.0 |
| R1 | 320 | 44 | round | 1.5-2.0 |
| R2 | 340 | 56 | round | 1.5-2.0 |
| チューブは仕様によって供給可能なサイズが異なります。 ナトリウムβアルミナは、上記記載の全サイズのご提供が可能です。 カリウムβアルミナは、100mm長が最大となります。 ストロンチウムβアルミナ、及び銀βアルミナは、A1, A2, H1, H3, H4のサイズのみご提供可能です。 チューブの品番は、下記例のように[形状コード-長さ-仕様コード]で示されます。 例：A1-70-LNZ, B2-220-MK, R2-340-LAg |
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Ionotec社製品使用文献
Solid State Sciences Volume 154, August 2024, 107630
Preparation and characterization of ion-exchanged Ni-Na-β”-Al2O3 and Fe-Na-β”-Al2O3 solid electrolytes for applications in liquid metals
https://www.sciencedirect.com/science/article/abs/pii/S129325582400195X?via%3Dihub
BIO Web of Conferences 129, 25020 (2024)
Microstructural Influence on Sodium Filament Growth in All Solid-state Batteries
https://www.bio-conferences.org/articles/bioconf/pdf/2024/48/bioconf_emc2024_25020.pdf
Jannis Küpper et al 2022 J. Electrochem. Soc. 169 060539
A Model of the Potassium-Oxygen Battery and its Application in Cathode Design
https://iopscience.iop.org/article/10.1149/1945-7111/ac797d
Energy Environ. Sci., 2022, 15, 4636-4646
A high-rate and high-efficiency molten-salt sodium–oxygen battery
https://pubs.rsc.org/en/content/articlehtml/2022/ee/d2ee01774a
Journal of Solid State Electrochemistry (2022) 26:1961–1968
High critical currents for dendrite penetration and voiding in potassium metal anode solid‑state batteries
https://link.springer.com/article/10.1007/s10008-022-05225-8
Andrew Dopilka et al 2021 J. Electrochem. Soc. 168 020516
Solid-State Electrochemical Synthesis of Silicon Clathrates Using a Sodium-Sulfur Battery Inspired Approach
https://iopscience.iop.org/article/10.1149/1945-7111/abdfe5/pdf
Cell Reports Physical Science 2, 100489, July 21, 2021
A high-voltage, low-temperature molten sodium battery enabled by metal halide catholyte chemistry
https://www.cell.com/cell-reports-physical-science/fulltext/S2666-3864(21)00189-2
Materials 2020, 13(2), 433
Large Planar Na-β″-Al2O3 Solid Electrolytes for Next Generation Na-Batteries
https://www.mdpi.com/1996-1944/13/2/433
Energy Technol. 2020, 8, 1901200
A Sodium Polysulfide Battery with Liquid/Solid Electrolyte: Improving Sulfur Utilization Using P2S5 as Additive and Tetramethylurea as Catholyte Solvent
https://d-nb.info/1260813606/34
Sci Rep. 2020 Jun 11;10:9453. doi: 10.1038/s41598-020-66410-1
Enhanced rate capabilities in a glass-ceramic-derived sodium all-solid-state battery
https://pmc.ncbi.nlm.nih.gov/articles/PMC7289851/
Communications Chemistry volume 2, Article number: 84 (2019)
A high-voltage concept with sodium-ion conducting β-alumina for magnesium-sodium dual-ion batteries
https://www.nature.com/articles/s42004-019-0186-4
Applied Catalysis B: Environmental Volume 243, April 2019, Pages 355-364
Electrochemical promotion for hydrogen production via ethanol steam reforming reaction
https://www.sciencedirect.com/science/article/abs/pii/S092633731831035X
The Royal Society of Chemistry 2018
Exploring Polycyclic Aromatic Hydrocarbons as Anolyte for Nonaqueous Redox Flow Batteries
https://www.rsc.org/suppdata/c8/ta/c8ta03221a/c8ta03221a1.pdf
Rakan F. Ashour et al 2017 J. Electrochem. Soc. 164 A535
Communication—Molten Amide-Hydroxide-Iodide Electrolyte for a Low-Temperature Sodium-Based Liquid Metal Battery
https://iopscience.iop.org/article/10.1149/2.1451702jes#back-to-top-target
取り扱い製品例
◎製品検索は表の上の検索ボックスをご利用ください。
| 品番 | 品名 |
|---|---|
| A1-70-LK | K beta"-alumina tube 6.5mm ID x 70mm length x 0.5mm thickness |
| A1-70-LN | Na beta"-alumina tube 6.5mm ID x 70mm length x 0.5mm thickness |
| A1-70-LN | Na beta"-alumina tube 6.5mm ID x 70mm length x 1mm thickness |
| A1-70-LNZ | Na beta"-alumina tube 6.5mm ID x 70mm length x 0.5mm thickness (strengthened composition) |
| A1-70-LNZ | Na beta"-alumina tube 6.5mm ID x 70mm length x 1mm thickness (strengthened composition) |
| A2-100-LL | Li beta-alumina tube 13mm ID x 100mm length x 1mm thickness |
| A2-100-LN | Na beta"-alumina tube 13mm ID x 100mm L, wt 1.0mm or 1.5mm |
| A4-100-LN | Na beta"-alumina tube. 4mmID x 100mm length x 0.6mm thickness : open end ID = 4mm - 4.05mm, closed end ID = 3.2mm - 3.5mm. Straightness is based on the tube allowing a tapered gauge of 4.0mm - 3.2mm x 95mm length to fit inside. |
| A4-100-LN (3-off) | Na beta"-alumina tube, 4mmID x 100mmL x 0.6mm wall thickness(3個) |
| A4-100-MN | Mg-stabilised Na beta"-alumina tube, 4mm ID x 100mm length x 0.5mm thickness : open end ID = 4mm - 4.05mm, closed end ID = 3.2mm - 3.5mm. Straightness is based on the tube allowing a tapered gauge of 4.0mm - 3.2mm x 95mm length to fit inside. |
| B1-100-LN | Na beta"-alumina tube 28mm ID x 100mm L x with flat closed end, wt 1.5mm |
| B1-100-LNZ | Na beta"-alumina tube 28mm ID x 100mm L x with flat closed end, wt 1.5mm (strengthened comp) |
| B2-200-LN | Na beta"-alumina tube 29mm ID x 200mm L, wt 1.5mm |
| B2-200-LN | Na beta"-alumina tube 29mm ID x 200mm L, wt 2.0mm |
| B2-220-LN | Na beta"-alumina tube, 29mm ID x 220mm L x with flat closed end, wt 1.5mm or 2.0mm （1本） |
| C2-220-LNZ | Na beta"-alumina tube, with round closed end, 52mm D x 220mm L |
| D10-0.5-LN | Na beta"-alumina disc, 10mm diameter x 0.5mm thickness |
| D10-0.5-LNZ | Na beta"-alumina disc, 10mm x 0.5mm thickness(strengthened composition) |
| D10-1-LN | Na beta"-alumina disc, 10mm diameter x 1mm thickness |
| D10-1-LNZ | Na beta"-alumina disc, 10mm diameter x 1mm thickness(strengthened composition) |
| D10-2-LN | Na beta"-alumina disc, 10mm diameter x 2mm thickness |
| D10-3-LN | Na beta"-alumina disc, 10mm diameter x 3mm thickness |
| D10-3-LNZ | Na beta"-alumina disc, 10mm diameter x 3mm thickness(strengthened composition) |
| D100-1-LNZ | Na beta"-alumina disc, 100mmD x 1.0mmT (strengthened composition) |
| D100-1.5-LNZ | Na beta"-alumina disc, 100mmD x 1.5mmT (strengthened composition) |
| D100-2-LNZ | Na beta"-alumina disc, 100mmD x 2mmT (strengthened composition) |
| D15-0.75-LNZ | Na beta"-alumina disc, 15mm x 0.75mm thickness(strengthened composition) |
| D15-1-LN | Na beta"-alumina disc, 15mm diameter x 1mm thickness |
| D16-0.75-LN | Na beta"-alumina disc, 16mm diameter x 0.75mm thickness |
| D16-0.75-LNZ | Na beta"-alumina disc, 16mm diameter x 0.75mm thickness (strengthened composition) |
| D18-1-LNZ | Na beta"-alumina disc, 18.0mm dia x 1.0mm thickness(strengthened composition) |
| D18-2-LNZ | Na beta"-alumina disc, 18.0mm dia x 2.0mm thickness(strengthened composition) |
| D19-1-LN | Na beta"-alumina disc, 19mm diameter x 1.0mm thickness |
| D20-1-LAg | Ag beta"-alumina disc, 20mm diameter x 1mm thickness |
| D20-1-LK | K beta"-alumina disc, 20mm diameter x 1mm thickness |
| D20-1-LKZ | K beta"-alumina disc, 20mm diameter x 1mm thickness |
| D20-1-LN | Na beta"-alumina disc, 20mm diameter x 1mm thickness |
| D20-1-LNZ | Na beta"-alumina disc, 20mm diameter x 1mm thickness (strengthened composition) |
| D20-1-LSr | Sr beta"-alumina disc, 20mm diameter x 1mm thickness |
| D24-1-LN | Na beta"-alumina disc, 24mm diameter x 1.0mm thickness |
| D25.4-2-LN | Na beta"-alumina disc, 25.4mm x 2.0mm thickness |
| D25.4-2-LNZ | Na beta"-alumina disc, 25.4mm x 2.0mm thickness(strengthened composition) |
| D45-1.5-LK | K beta"-alumina disc (Li-stabilised), 45x1.5mm, |
| D45-1.5-LL | Li beta-alumina discs, 45mm x 1.5mm thickness |
| D45-1.5-LN | Na beta"-alumina disc, 45mm x 1.5mm thickness |
| D45-1.5-MK | K beta"-alumina disc (Mg-stabilised), 45x1.5mm |
| D70-1-LNZ | Na beta"-alumina disc (strengthened composition), 70mmD x 1.0mmT |
| D70-1.5-LN | Na beta"-alumina disc, 70mm diameter x 1.5mm thickness |
| D70-2-LN | Na beta"-alumina disc, 70mm diameter x 2.0mm thicknes |
| H1-40-LN | Na beta"-alumina tube, 20mmID x 40mmL, with flat closed end (nominal wall thickness 1.0 or 1.5mm) （1本） |
| H4-100-LN | Na beta"-alumina tube, 20mmID x 100mmL x with flat closed end x 1mmT |
| P10-0.5-LN | Na beta"-alumina plate, 10mm x 10mm x 0.5mm thickness |
| P10-0.5-MN | Mg stabilised Na beta"-alumina plate, 10x10x0.5mm |
| P10-１-LK | K beta"-alumina plate 10 x 10 x 1mm thickness |
| P10-1-LNZ | Na beta"-alumina plate, 10mm x 10mm x 1mm (strengthened composition) |
| P10-2-LNZ | Na beta"-alumina plate, 10mm x 10mm x 2mm (strengthened composition) |
| P10/50-1-LN | Na beta"-alumina plate, 10mm x 50mm x 1mm thickness |
| P12-0.5-LN | Na beta"-alumina plate, 12mm x 12mmx 0.5mm thickness |
| P12-0.5-LNZ | Na beta"-alumina plate (strengthened composition), 12mm x 12mmx 0.5mm thickness |
| P12-0.7-LN | Na beta"-alumina plate, 12mm x 12mmx 0.７mm thickness |
| P20-1-LNZ | Na beta"-alumina plate, 20mm x 20mm x 1mm (strengthened composition) |
| P20-2-LNZ | Na beta"-alumina plate, 20mm x 20mm x 2mm (strengthened composition) |
| P24-0.7-LNZ | Na beta"-alumina plate (strengthened composition) 24mm x 24mm x 0.7mm thickness |
| P24-1-LN | Na beta"-alumina plate, 24mm x 24mm x 1.0mm thickness |
| P24-1.5-LN | Na beta"-alumina plate, 24mm x 24mm x 1.5mm thickness |
| P24-2-LN | Na beta"-alumina plate, 24mm x 24mm x 2.0mm thickness |
| P24-2.5-LN | Na beta"-alumina plate, 24mm x 24mm x 2.5mm thickness |
| P24-3-LN | Na beta"-alumina plate, 24mm x 24mm x 3.0mm thickness |
| P25-1-LN | Na beta"-alumina plate, 25mm x 25mm x 1.0mm thickness |
| P36-1-LN | Na beta"-alumina plate 36mm x 36mm x 1mm thickness |
| P50-1-LN | Na beta"-alumina plate 50mm x 50mm x 1mm thickness |
| P50-1-LNZ | Na beta"-alumina plate, 50mm x 50mm x 1.0mmT (strengthened composition) |
| P70-1-LNZ | Na beta"-alumina plate, 70mm x 70mm x 1.0mmT (strengthened composition) |
| 品番 | 品名 |